Click on the Show Profiles button-

Here you can see all the outlook profile which will previously configured. You can ignore this and click on the Add button to begin to create a new profile.
Outlook will now ask you to give the profile a name. Type your first initial and last name here and click OK button.

Now email configuration window appears on you screen as below-

Kindly fill all the necessary details about email configuration and click on NEXT button.

Once Outlook validate your provided details then add your email account into Outlook.